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(If using a box mix, prepare the batter according to the directions on the back of the box--I suggest Ghirardelli boxed brownie mix or Betty Crocker).
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Over a double broiler, or in the microwave, melt butter and chocolate together. Once melted, allow to cool about 10 minutes.
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Next, add in the sugar, and mix. Add in eggs, one at a time, stirring after each addition. Next, add in vanilla.
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Add in espresso powder, salt, baking powder, flour, and cocoa powder. Mix until just combined.
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Add in oil and chocolate chips, stir.
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Pour 2/3 of the batter into the baking pan. Sprinkle 1 cup of marshmallows evenly over the batter. Top the marshmallows with the rest of the batter, doing your best to cover all the marshmallows with batter.
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Bake for 25-30 minutes, or until brownies are no longer wet in the middle.
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Pull the brownies out of the oven and top with graham cracker pieces and chopped chocolate.
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Bake for 1 minute.
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Allow the brownies to cool and enjoy!