Combine cocoa and hot coffee together, stirring until smooth; add in oil and stir; set aside.
Beat butter with a standing mixer or hand mixer until creamy and fluffy, about 2-3 minutes. Gradually add in white and brown sugar, beating about 3 minutes until it is light and fluffy. Add eggs, 1 at a time, beating just until the yellow disappears.
Add in chocolate/coffee mixture, and beat until just combined.
In a bowl, sift together flour, baking soda, baking powder, salt, and espresso powder.
Stir together buttermilk, vanilla extract, and sour cream (or Greek yogurt).
Alternately mix the buttermilk mixture and flour mixture with the butter batter, beginning and ending with the flour mixture. Do not overmix--stir until everything is just combined.
Fill two cake pans about 1/4 of the way full with the chocolate batter. Place 7 Oreos (14 all together) in each of the two cake pans, evenly spread apart (I did 6 in a circle, and 1 in the middle). Divide the remaining batter between the two cake pans. Tap the cake pans to remove any air bubbles.
Bake for 25-30 minutes, or until a cake tester comes out clean.